SS05ROTN - v1.0.6

Dataset Id: XKQ9jNTJNH16EFtU5kZP

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iso2k-1_1_2

root

archiveType: Sclerosponge

originalDataUrl: https://www.ncdc.noaa.gov/paleo/study/1920

lipdVersion: 1.3

pub
pub1

author: list(name = "Rosenheim, Brad E.")

journal: Geophysical Research Letters

volume: 32

title: Salinity change in the subtropical Atlantic: Secular increase and teleconnections to the North Atlantic Oscillation

doi: 10.1029/2004GL021499

pub2

author: list(list(name = "Rosenheim, Brad E."), list(name = "Swart, Peter K."), list(name = "Thorrold, Simon R."), list(name = "Willenz, Philippe"), list(name = "Berry, Lorraine"), list(name = "Latkoczy, Christopher"))

journal: Geology

volume: 32

pages: 145

title: High-resolution Sr/Ca records in sclerosponges calibrated to temperature in situ

doi: 10.1130/G20117.1

pub3

author: list(list(name = "Swart, P. K."), list(name = "Thorrold, S."), list(name = "Rosenheim, B."), list(name = "Eisenhauer, A."), list(name = "Harrison, C. G. A."), list(name = "Grammer, M."), list(name = "Latkoczy, C."))

journal: Paleoceanography

volume: 17

pages: 17-1-17-12

title: Intra-annual variation in the stable oxygen and carbon and trace element composition of sclerosponges

doi: 10.1029/2000PA000622

geo

latitude: 23.92

longitude: -76.83

elevation: -143

siteName: Tongue of the Ocean, Bahamas

PaleoData columns
year (yr AD)

TSid: MATdb727c687b

variableName: year

units: yr AD

description: Year AD

d18O (permil)

TSid: SS05ROTN02A

variableName: d18O

units: permil

description: carbonate

interpretation
1

basis: we find secular salinity increases of 0.35 A± 0.34 psu in Exuma Sound and 0.5 A± 0.35 psu in TOTO that must happen coevally with the secular temperature increases to explain the discrepancies between Sr/Ca and d18Oaragonite linear temperature trends. It is evident from (4) that our reconstruction is sensitive to the gradient d18Osw/S (0.54 %psu1). Despite the significant cumulative residual error from equations (1)a€“(3) (auxiliary material), our data clearly identify salinity variation in the subsurface waters of both Exuma Sound and TOTO during the last 100 years.

direction: decrease

interpDirection: decrease

scope: climate

variable: temperature

variableDetail: subsurface, 143 m

variableGroup: temperature and salinity

2

scope: climate

3

scope: climate

4

basis: bohm 2000 10.1016/S0016-7037(99)00408-1

coefficient: NA

direction: negative

equilibriumEvidence: mode of skeleton formation of Ceratoporella nicholsoni suggest that these sponges precipitate aragonite close to isotopic equilibrium (bohm, 2000).

fraction: NA

inferredMaterial: seawater

integrationTime: 1

integrationTimeBasis: sclerosponges were dated using U/Th radiometric techniques and then analyzed using high resolution micromilling for oxygen isotope analysis via isotope ratio mass spectrometry and laser ablation sampling for Sr/Ca analysis via ICP-MS. Constant-growth age models constructed from U/Th dating indicate growth rates of 145 mmy1 for the Exuma sclerosponge and 172 mmy1 for the TOTO sclerosponge (auxiliary material1). The radiometric age model of the TOTO sclerosponge was tuned to annual Sr/ Ca variations after Swart et al. [2002], however because tuned age models and constant growth models are within 5% [Swart et al., 2002], the U/Th constant growth model was used for the Exuma sclerosponge.

integrationTimeUncertainty: subannual samples averaged to annual for archived data

integrationTimeUncertaintyType: U/Th dating and Sr/Ca for annual cycles to define chronology

integrationTimeUnits: year

mathematicalRelation: linear

rank: 1

scope: isotope

variable: temperature

variableGroup: Temperature

variableGroupDirection: negative

variableGroupOriginal: T_water

5

basis: Oxygen isotope values (d18O) are measured in %VPDB for aragonite and % SMOW for water. Ratios of Sr/Ca are measured in mmolmol1, temperature (T) is in C, and salinity (S) is in psu. Equation (3) is constructed from surface waters (<50 m) of the return flow of the N. Atlantic Gyre between 45N and 31N. During transport between these latitudes, this water mass begins adopting the properties of the SMW [Krauss, 1986; Ottens, 1991]. By combining and rearranging these equations to reconstruct the salinity record preserved in Bahamas sclerosponges,

coefficient: NA

direction: negative

equilibriumEvidence: mode of skeleton formation of Ceratoporella nicholsoni suggest that these sponges precipitate aragonite close to isotopic equilibrium (bohm, 2000).

fraction: NA

inferredMaterial: seawater

integrationTime: 1

integrationTimeBasis: sclerosponges were dated using U/Th radiometric techniques and then analyzed using high resolution micromilling for oxygen isotope analysis via isotope ratio mass spectrometry and laser ablation sampling for Sr/Ca analysis via ICP-MS. Constant-growth age models constructed from U/Th dating indicate growth rates of 145 mmy1 for the Exuma sclerosponge and 172 mmy1 for the TOTO sclerosponge (auxiliary material1). The radiometric age model of the TOTO sclerosponge was tuned to annual Sr/ Ca variations after Swart et al. [2002], however because tuned age models and constant growth models are within 5% [Swart et al., 2002], the U/Th constant growth model was used for the Exuma sclerosponge.

integrationTimeUncertainty: subannual samples averaged to annual for archived data

integrationTimeUncertaintyType: U/Th dating and Sr/Ca for annual cycles to define chronology

integrationTimeUnits: year

mathematicalRelation: linear

rank: 2

scope: isotope

variable: salinity

variableGroup: EffectiveMoisture

variableGroupDirection: negative

variableGroupOriginal: salinity_seawater

6

coefficient: NA

fraction: NA

rank: NA

scope: isotope

Sr/Ca (unitless)

TSid: RYiV0il9NAZ

variableName: Sr/Ca

units: unitless

interpretation
1

scope: climate

2

scope: climate

3

scope: climate

4

coefficient: NA

fraction: NA

rank: NA

scope: isotope

5

coefficient: NA

fraction: NA

rank: NA

scope: isotope

6

coefficient: NA

fraction: NA

rank: NA

scope: isotope

ChronData columns
depthUTh (mm)

TSid: chron1

variableName: depthUTh

units: mm

description: mid-point depth of the sub-sample drilled for U-Th age

SampleID (unitless)

TSid: chron2

variableName: SampleID

units: unitless

description: Sample ID for the U-Th age measured

Th232 (ppt)

TSid: chron6

variableName: Th232

units: ppt

description: 232Th content of the sub-sample

Th232_error (ppt)

TSid: chron7

variableName: Th232_error

units: ppt

description: Analytical uncertainty of 232Th

age (years ago)

TSid: chron16

variableName: age

units: years ago

description: Corrected U-Th age of the sub-sample

AgeCorr_error (yrs)

TSid: chron17

variableName: AgeCorr_error

units: yrs

description: Uncertainty of Corrected Age (includes Th correction)

230Th/234U (ratio)

TSid: chron30

variableName: 230Th/234U

units: ratio

description: unitless ratio, activity ratio of 230Th to 234U

230Th/234U error (unitless)

TSid: chron31

variableName: 230Th/234U error

units: unitless

description: unitless ratio, two standard deviations of the mean 230Th/234U activity ratio

234U/238U (ratio)

TSid: chron32

variableName: 234U/238U

units: ratio

description: unitless ratio, activity ratio of 234U to 238U

234U/238U error (unitless)

TSid: chron33

variableName: 234U/238U error

units: unitless

description: unitless ratio, two standard deviations of the mean 234U/238U activity ratio