LS13BAFL - v1.0.5

Dataset Id: 4syMlQhjtDBSmmPBfUqd

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R code to load dataset:

L <- lipdR::readLipd("https://lipdverse.org/data/4syMlQhjtDBSmmPBfUqd/1_0_5/LS13BAFL.lpd")

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In compilations: (only most recent versions are shown)

iso2k-1_1_1

root

archiveType: LakeSediment

originalDataUrl: https://www.ncdc.noaa.gov/paleo/study/14513

lipdVersion: 1.3

pub
pub1

author: Balascio, N. L. , DAndrea, W. J. , Bradley, R. S. , Perren, B. B.

journal: The Holocene

volume: 23

pages: 14281439

title: Biogeochemical evidence for hydrologic changes during the Holocene in a lake sediment record from southeast Greenland

doi: 10.1177/0959683613493938

geo

latitude: 65.6107

longitude: -37.6935

elevation: 73

siteName: Flower Valley Lake

PaleoData columns
year (yr AD)

TSid: MAT27bb9b76f9

variableName: year

units: yr AD

description: Year AD

interpretation
1

rank: NA

scope: climate

2

rank: NA

scope: climate

depth (cm)

TSid: MATed1402b6a1

variableName: depth

units: cm

description: depth

interpretation
1

rank: NA

scope: climate

2

rank: NA

scope: climate

d2H (permil)

TSid: LS13BAFL01D

variableName: d2H

units: permil

description: terrestrial biomarker

interpretation
1

scope: climate

variable: deleteMe

variableGroup: not interpreted to reflect climate (note by Iso2k compiler: dD precip does not change seasonally in this part of Greenland, likely because source areas are proximal and carry relatively enriched moisture to this region throughout the year)

2

scope: climate

3

scope: climate

4

basis: Winter snow melting during growing season. "dD values of long-chain n-alkanes (dDwax) reflect dD of water used by terrestrial vegetation after modification by biosynthetic processes (Sachse et al., 2012 and references therein). Soil moisture provides the source water for terrestrial plants, while lake water is the source for aquatic macrophytes and algae. dD of water in soils can be modified to some extent from dD of annual precipitation by evaporation. However, it has been shown that dDwax is unaltered by plants following leaf formation and therefore reflects dDwater used during leaf flush (Kahmen et al., 2011; Sachse et al., 2010; Tipple et al., 2013). In the Arctic, the majority of leaf formation takes place in late spring/early summer following the return of appreciable sunlight. Because snowmelt is the predominant water source available to plants at the time of leaf formation, the dDwax is potentially biased toward wintertime dDp (i.e. snowfall months). In Tasiilaq, the difference between precipitation-weighted annual average dDp (?92?) and precipitation- weighted average dDp during months with below zero average temperatures (October-April; ?96?) is negligible (Bowen, 2008; Cappelen et al., 2011), and thus, any changes in the timing of leaf formation during the Holocene, or in the seasonality of precipitation, are unlikely to have had much impact on dDwax."

direction: positive

inferredMaterial: soil water

mathematicalRelation: linear

rank: 1

scope: isotope

seasonality: Dec-Feb

variable: precipitationIsotope

variableGroup: P_isotope

variableGroupDirection: positive

5

direction: negative

inferredMaterial: soil water

scope: isotope

6

scope: isotope

d2H (permil)

TSid: LS13BAFL01B

variableName: d2H

units: permil

description: aquatic biomarker

interpretation
1

basis: The extent of isotopic enrichment of surface waters from meteoric water is determined by the degree of evaporative enrichment of the water body (Leng and Anderson, 2003). Therefore, ... the ?D of lipids produced by aquatic plants (?Daq) tracks the degree of evaporative isotopic enrichment of lake water from meteoric water...."The relatively D-enriched values (more positive ?D) of ?D25 and ?D27 are consistent with our interpretation that these compounds reflect isotopically enriched lake water."

direction: negative

interpDirection: negative

scope: climate

seasonality: Summer

variable: effectivePrecipitation

variableDetail: air@surface

variableDetailOriginal: air

variableGroup: moisture balance (P-E)

2

scope: climate

3

scope: climate

4

basis: dD values of long-chain n-alkanes (dDwax) reflect dD of water used by terrestrial vegetation after modification by biosynthetic processes (Sachse et al., 2012 and references therein). Soil mois- ture provides the source water for terrestrial plants, while lake water is the source for aquatic macrophytes and algae. dD of water in soils can be modified to some extent from dD of annual precipitation by evaporation. However, it has been shown that dDwax is unaltered by plants following leaf formation and there- fore reflects dDwater used during leaf flush (Kahmen et al., 2011; Sachse et al., 2010; Tipple et al., 2013). In the Arctic, the majority of leaf formation takes place in late spring/early summer follow- ing the return of appreciable sunlight. Because snowmelt is the predominant water source available to plants at the time of leaf formation, the dDwax is potentially biased toward wintertime dDp (i.e. snowfall months). In Tasiilaq, the difference between precipitation-weighted annual average dDp (?92?) and precipitation- weighted average dDp during months with below zero average temperatures (October-April; ?96?) is negligible (Bowen, 2008; Cappelen et al., 2011), and thus, any changes in the timing of leaf formation during the Holocene, or in the seasonality of precipita- tion, are unlikely to have had much impact on dDwaxd

direction: negative

mathematicalRelation: linear

rank: 1

scope: isotope

seasonality: Dec-Feb

variable: hydrologicBalance

variableGroup: EffectiveMoisture

variableGroupDirection: negative

variableGroupOriginal: I_E

5

basis: see interpretation for independentParameter1

direction: negative

mathematicalRelation: linear

rank: 2

scope: isotope

seasonality: Dec-Feb

variable: precipitationIsotope

variableGroup: P_isotope

variableGroupDirection: positive

6

scope: isotope

d2H (permil)

TSid: LS13BAFL01C

variableName: d2H

units: permil

description: terrestrial biomarker

interpretation
1

scope: climate

variable: deleteMe

variableGroup: not interpreted to reflect climate (note by Iso2k compiler: dD precip does not change seasonally in this part of Greenland, likely because source areas are proximal and carry relatively enriched moisture to this region throughout the year)

2

scope: climate

3

scope: climate

4

basis: dD values of long-chain n-alkanes (dDwax) reflect dD of water used by terrestrial vegetation after modification by biosynthetic processes (Sachse et al., 2012 and references therein). Soil moisture provides the source water for terrestrial plants, while lake water is the source for aquatic macrophytes and algae. dD of water in soils can be modified to some extent from dD of annual precipitation by evaporation. However, it has been shown that dDwax is unaltered by plants following leaf formation and therefore reflects dDwater used during leaf flush (Kahmen et al., 2011; Sachse et al., 2010; Tipple et al., 2013). In the Arctic, the majority of leaf formation takes place in late spring/early summer following the return of appreciable sunlight. Because snowmelt is the predominant water source available to plants at the time of leaf formation, the dDwax is potentially biased toward wintertime dDp (i.e. snowfall months). In Tasiilaq, the difference between precipitation-weighted annual average dDp (?92?) and precipitation- weighted average dDp during months with below zero average temperatures (October-April; ?96?) is negligible (Bowen, 2008; Cappelen et al., 2011), and thus, any changes in the timing of leaf formation during the Holocene, or in the seasonality of precipita- tion, are unlikely to have had much impact on dDwaxd

direction: positive

mathematicalRelation: linear

rank: 1

scope: isotope

seasonality: Dec-Feb

variable: precipitationIsotope

variableGroup: P_isotope

variableGroupDirection: positive

5

direction: negative

scope: isotope

6

scope: isotope

d2H (permil)

TSid: LS13BAFL01A

variableName: d2H

units: permil

description: aquatic biomarker

interpretation
1

basis: The extent of isotopic enrichment of surface waters from meteoric water is determined by the degree of evaporative enrichment of the water body (Leng and Anderson, 2003). Therefore, ... the ?D of lipids produced by aquatic plants (?Daq) tracks the degree of evaporative isotopic enrichment of lake water from meteoric water...."The relatively D-enriched values (more positive ?D) of ?D25 and ?D27 are consistent with our interpretation that these compounds reflect isotopically enriched lake water."

interpDirection: negative

scope: climate

seasonality: Summer

variable: effectivePrecipitation

variableDetail: air@surface

variableDetailOriginal: air

variableGroup: moisture balance (P-E)

2

scope: climate

3

scope: climate

4

basis: ?D values of long-chain n-alkanes (?Dwax) reflect ?D of water used by terrestrial vegetation after modification by biosynthetic processes (Sachse et al., 2012 and references therein). Soil mois- ture provides the source water for terrestrial plants, while lake water is the source for aquatic macrophytes and algae. ?D of water in soils can be modified to some extent from ?D of annual precipitation by evaporation. However, it has been shown that ?Dwax is unaltered by plants following leaf formation and there- fore reflects ?Dwater used during leaf flush (Kahmen et al., 2011; Sachse et al., 2010; Tipple et al., 2013). In the Arctic, the majority of leaf formation takes place in late spring/early summer follow- ing the return of appreciable sunlight. Because snowmelt is the predominant water source available to plants at the time of leaf formation, the ?Dwax is potentially biased toward wintertime ?Dp (i.e. snowfall months). In Tasiilaq, the difference between precip- itation-weighted annual average ?Dp (?92?) and precipitation- weighted average ?Dp during months with below zero average temperatures (October?April; ?96?) is negligible (Bowen, 2008; Cappelen et al., 2011), and thus, any changes in the timing of leaf formation during the Holocene, or in the seasonality of precipita- tion, are unlikely to have had much impact on ?Dwax.

direction: negative

mathematicalRelation: linear

scope: isotope

seasonality: Growing Season

5

basis: see interpretation for independentParameter1

direction: negative

mathematicalRelation: linear

scope: isotope

seasonality: Winter

6

scope: isotope

ChronData columns
depth (cm)

TSid: chron1

variableName: depth

units: cm

description: midpoint depth

age14C (yr14C BP)

TSid: chron2

variableName: age14C

units: yr14C BP

description: 14C years before 1950

SD (yr14C BP)

TSid: chron3

variableName: SD

units: yr14C BP

description: 14C years uncertainty

fractionModern ()

TSid: chron4

variableName: fractionModern

description: fraction of modern 14C activity

fractionModernUncertainty ()

TSid: chron5

variableName: fractionModernUncertainty

description: fraction of modern 14C activity uncertainty

delta13C (permil)

TSid: chron6

variableName: delta13C

units: permil

description: delta13C of material analyzed for 14C

delta13Cuncertainty (permil)

TSid: chron7

variableName: delta13Cuncertainty

units: permil

description: delta13C uncertainty

thickness (cm)

TSid: chron8

variableName: thickness

units: cm

description: thickness of sample (along depth axis)

labID ()

TSid: chron9

variableName: labID

description: laboratory ID from radiocarbon facility

materialDated ()

TSid: chron10

variableName: materialDated

description: material analyzed

activity (Bq g1)

TSid: chron11

variableName: activity

units: Bq g1

description: 210Pb, 239+240Pu or 137Cs activity

activityUncertainty (Bq g1)

TSid: chron12

variableName: activityUncertainty

units: Bq g1

description: 210Pb, 239+240Pu or 137Cs activity uncertainty

supportedActivity ()

TSid: chron13

variableName: supportedActivity

description: Y if supported 210Pb activity, N if unsupported 210Pb activity

x210PbModel ()

TSid: chron14

variableName: x210PbModel

description: model used to convert 210Pb activity to age (e.g., constant rate of supply)

age (yr BP)

TSid: chron15

variableName: age

units: yr BP

description: years before 1950 (calibrated age, or ages that dont need calibration)

SD (yr BP)

TSid: chron16

variableName: SD

units: yr BP

description: uncertainty in age

reservoirAge14C (yr14C BP)

TSid: chron17

variableName: reservoirAge14C

units: yr14C BP

description: 14C reservoir age

reservoirAge14CUncertainty (yr14C BP)

TSid: chron18

variableName: reservoirAge14CUncertainty

units: yr14C BP

description: 14C reservoir age uncertainty

useInAgeModel ()

TSid: chron19

variableName: useInAgeModel

description: was this date used in the age modelpermil